**First hazard class (table row):** 5.1

**Second hazard class (table column):** 4.1

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 1

**What the code requires:** 1—“Away from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 4.2

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>

5.1 — Hazmat load segregation — which hazard classes may travel together, highway vs vessel


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 4.3

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 5.1

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 5.2

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 6.1

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 1

**What the code requires:** 1—“Away from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 6.2

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 3

**What the code requires:** 3—“Separated by a complete compartment or hold from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 7

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 1

**What the code requires:** 1—“Away from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 8

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 5.1

**Second hazard class (table column):** 9

**Row description:** Oxidizing substances

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 1.1, 1.2, 1.5

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>

2.3 — Hazmat load segregation — which hazard classes may travel together, highway vs vessel


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 1.3

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 1.4, 1.6

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 1

**What the code requires:** 1—“Away from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 2.1

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 2.2

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 2.3

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 3

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 4.1

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 4.2

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 4.3

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 5.1

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 5.2

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 6.1

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 6.2

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 7

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** 1

**What the code requires:** 1—“Away from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 8

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 2.3

**Second hazard class (table column):** 9

**Row description:** Poisonous gases

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 1.1, 1.2, 1.5

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>

6.1 — Hazmat load segregation — which hazard classes may travel together, highway vs vessel


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 1.3

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** 2

**What the code requires:** 2—“Separated from.”

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 1.4, 1.6

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 2.1

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 2.2

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 2.3

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>


**First hazard class (table row):** 6.1

**Second hazard class (table column):** 3

**Row description:** Poisons

**Transport mode:** Carriage by Vessel

**Segregation code:** X

**What the code requires:** X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table.

> General Segregation Requirements for Hazardous Materials [Segregation must also take account of a single secondary hazard label, as required by <https://www.ecfr.gov/current/title-49/section-176.83#p-176.83(a)(6)> paragraph (a)(6) of this section.] Class | 1.1, 1.2, 1.5 | 1.3 | 1.4, 1.6 | 2.1 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 6.2 | 7 | 8 | 9 | Explosives, 1.1, 1.2, 1.5 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 4 | 4 | 4 | 4 | 4 | 2 | 4 | 2 | 4 | X | Explosives, 1.3 | (*) | (*) | (*) | 4 | 2 | 2 | 4 | 3 | 3 | 4 | 4 | 4 | 2 | 4 | 2 | 2 | X | Explosives, 1.4, 1.6 | (*) | (*) | (*) | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 4 | 2 | 2 | X | Flammable gases 2.1 | 4 | 4 | 2 | X | X | X | 2 | 1 | 2 | 2 | 2 | 2 | X | 4 | 2 | 1 | X | Non-toxic, non-flammable gases 2.2 | 2 | 2 | 1 | X | X | X | 1 | X | 1 | X | X | 1 | X | 2 | 1 | X | X | Poisonous gases 2.3 | 2 | 2 | 1 | X | X | X | 2 | X | 2 | X | X | 2 | X | 2 | 1 | X | X | Flammable liquids 3 | 4 | 4 | 2 | 2 | 1 | 2 | X | X | 2 | 2 | 2 | 2 | X | 3 | 2 | X | X | Flammable solids 4.1 | 4 | 3 | 2 | 1 | X | X | X | X | 1 | X | 1 | 2 | X | 3 | 2 | 1 | X | Spontaneously combustible substances 4.2 | 4 | 3 | 2 | 2 | 1 | 2 | 2 | 1 | X | 1 | 2 | 2 | 1 | 3 | 2 | 1 | X | Substances which are dangerous when wet 4.3 | 4 | 4 | 2 | 2 | X | X | 2 | X | 1 | X | 2 | 2 | X | 2 | 2 | 1 | X | Oxidizing substances 5.1 | 4 | 4 | 2 | 2 | X | X | 2 | 1 | 2 | 2 | X | 2 | 1 | 3 | 1 | 2 | X | Organic peroxides 5.2 | 4 | 4 | 2 | 2 | 1 | 2 | 2 | 2 | 2 | 2 | 2 | X | 1 | 3 | 2 | 2 | X | Poisons 6.1 | 2 | 2 | X | X | X | X | X | X | 1 | X | 1 | 1 | X | 1 | X | X | X | Infectious substances 6.2 | 4 | 4 | 4 | 4 | 2 | 2 | 3 | 3 | 3 | 2 | 3 | 3 | 1 | X | 3 | 3 | X | Radioactive materials 7 | 2 | 2 | 2 | 2 | 1 | 1 | 2 | 2 | 2 | 2 | 1 | 2 | X | 3 | X | 2 | X | Corrosives 8 | 4 | 2 | 2 | 1 | X | X | X | 1 | 1 | 1 | 2 | 2 | X | 3 | 2 | X | X | Miscellaneous dangerous substances 9 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | Numbers and symbols relate to the following terms as defined in this section: | 1—“Away from.” | 2—“Separated from.” | 3—“Separated by a complete compartment or hold from.” | 4—“Separated longitudinally by an intervening complete compartment or hold from.” | X—The segregation, if any, is shown in the <https://www.ecfr.gov/current/title-49/section-172.101> § 172.101 table. | *—See <https://www.ecfr.gov/current/title-49/part-176/section-176.144> § 176.144 of this part for segregation within Class 1. |

Source: <https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-176/subpart-D/section-176.83>