Reference Source

Gas group, temperature class and autoignition temperature by substance

Hazardous area (explosive atmosphere) classification of individual flammable gases, vapours and combustible dusts. Each record is one substance as classified by one publisher, giving the apparatus / gas group (IIA, IIB, IIC, IIB+H2 under IEC 60079 and ATEX, or Class I Group A/B/C/D under the US National Electrical Code), the temperature class (T1 to T6), and the autoignition temperature the publisher prints. Answers 'is toluene IIA or IIB', 'what temperature class is acetone', 'MEK autoignition temperature for explosion proof equipment', 'NEC Group C equivalent IEC gas group', 'what gas group is hydrogen sulphide', and 'ethylene gas group and T class'. Publishers disagree on the autoignition temperature of the same substance -- hydrogen is printed as 500 C, 520 C and 560 C by three different manufacturers, and ethylene as 450 C and 490 C -- and because the temperature class is derived from that number the disagreement changes which equipment is legal to install. Every value is quoted from the page that printed it and attributed, so the disagreements are visible rather than averaged away.

Records60
Sources4
Verified2026-08-06
Review by2028-08-05
LicenceFacts extracted from freely published manufacturer and industry reference pages. Gas group and temperature class assignments are safety classifications and the underlying values are facts, not copyrightable expression. The authoritative documents (NFPA 497, IEC 60079-20-1) are not reproduced and were not opened -- the fact is taken, never the document. No bulk take from any single source: records come one or two substances at a time from five separate publishers.

1 record where two or more sources state different values. Both sides are reproduced on the record page, each with its own source and quote.

The data

SubstanceClassification systemApparatus / gas groupTemperature classIgnition temperature (C)Ignition temperature (F)Dust layer ignition temperature (C)
Di-ethyl etherIEC / ATEXIIBT4160
BenzaldehydeIEC / ATEXIIAT4192
CyclohexaneIEC / ATEXIIAT3245
GasolineIEC / ATEXIIA280536
Gasoline (petrol)IEC / ATEXIIAT3280
GasolineNEC 500 (North America)D280536
KeroseneIEC / ATEXIIAT3295
Acetylenesources differIEC / ATEXIICT2305
AcetyleneNEC 500 (North America)A305581
Ethanol (ethyl alcohol)IEC / ATEXIIAT2365
Propan-1-ol (n-propyl alcohol)IEC / ATEXIIBT2371
Coal dust (lignite)IEC / ATEXIIIB380225
Propan-2-ol (iso-propyl alcohol)IEC / ATEXIIAT2399
ButaneIEC / ATEXIIAT2405
Methyl celluloseIEC / ATEXIIIB420320
PolytheneIEC / ATEXIIIB420(melts)
Acetic acidIEC / ATEXIIAT1427
EthyleneIEC / ATEXIIB450842
EthyleneNEC 500 (North America)C450842
StarchIEC / ATEXIIIB460435
XyleneIEC / ATEXIIAT1463
AcetoneIEC / ATEXIIAT1465
Methanol (methyl alcohol)IEC / ATEXIIAT2470
PropaneIEC / ATEXIIAT1470
EthyleneIEC / ATEXIIBT2490
FlourIEC / ATEXIIIB490340
SugarIEC / ATEXIIIB490460
HydrogenIEC / ATEXIICT1500
Methyl ethyl ketone (MEK)IEC / ATEXIIBT2505
Grain dustIEC / ATEXIIIB510300
HydrogenIEC / ATEXIIC520968
HydrogenNEC 500 (North America)B520968
Phenolic resinIEC / ATEXIIIB530>450
TolueneIEC / ATEXIIAT1535
HydrogenIEC / ATEXIICT1560
Methane (natural gas) (non-mining)IEC / ATEXIIAT1580
AluminiumIEC / ATEXIIIC590>450
AmmoniaIEC / ATEXIIAT1651
PVCIEC / ATEXIIIB700>450
SootIEC / ATEXIIIB810570
Carbon DisulphineIEC / ATEXIICT695
AcetoneIEC / ATEXIIA
AcetyleneIEC / ATEXIIC
AmmoniaIEC / ATEXIIA
BenzeneIEC / ATEXIIA
ButaneIEC / ATEXIIA
Carbon disulphideIEC / ATEXIIC
DieselIEC / ATEXIIA
Diethyl etherIEC / ATEXIIB
EthanolIEC / ATEXIIA
EthyleneIEC / ATEXIIB
Ethylene oxideIEC / ATEXIIB
HydrogenIEC / ATEXIIC
Hydrogen sulphideIEC / ATEXIIB
MethaneIEC / ATEXIIA
n-HexaneIEC / ATEXIIA
PropaneIEC / ATEXIIA
TolueneIEC / ATEXIIA
Town gasIEC / ATEXIIB
XyleneIEC / ATEXIIA

Where this came from

Every record above links the page it was taken from and quotes the sentence that states it. These are the 4 sources this dataset was assembled from.

Machine-readable

60 records. last verified against source 2026-08-06. due for re-check by 2028-08-05.

Licence. Facts extracted from freely published manufacturer and industry reference pages. Gas group and temperature class assignments are safety classifications and the underlying values are facts, not copyrightable expression. The authoritative documents (NFPA 497, IEC 60079-20-1) are not reproduced and were not opened -- the fact is taken, never the document. No bulk take from any single source: records come one or two substances at a time from five separate publishers.